One‐Pot Synthesis of Aliphatic Nitro Compounds by Michael/retro‐Claisen Fragmentation Domino Reaction

A novel and concise method for the construction of γ‐nitro ketones and 1,3‐dinitro compounds with chemoselective acyl transfer has been presented under basic conditions via one‐pot reactions. These reactions feature high atom‐ and step‐economic possess, mild condition and simple operation for one‐pot synthesis of aliphatic nitro compounds. This protocol provides the products in good yields. The possible reaction mechanism has also been proposed.     

Medium effect on dielectric relaxation behaviors of 4A zeolite bulk dispersion system

Dielectric spectra of 4A zeolite particles bulked in deionized water (4A/W) or cyclohexane (4A/C) were measured respectively under different temperatures, and two dielectric relaxations were found in both of 4A/W and 4A/C. Because of existence of water molecules in pores, both low and high frequency relaxation times (τ_LFR and τ_HFR) of 4A/Wdecreasedmore sharply than 4A/C with increasing temperature. According to the temperature dependence of τ_LFR and τ_HFR, the activation energies of Na⁺ interacting with framework under hydrated and dehydrated environments were calculated respectively, and the original properties of Na⁺ in dehydrated zeolite were obtained by analyzing the dielectric properties of 4A/C. Furthermore, a transient state of Na⁺ motion with temperature was found in 4A/C system.     

考虑横向剪切变形的扁球壳在集中力作用下的分析

采用适于夹层壳的直线假设扁壳理论，应用三角级数法，导出了扁球壳齐次方程的解析解。进而分析了在顶点作用法向集中力和在偏心集中力作用下的解。计算了在偏心集中力作用下带孔球壳的位移和应力，并将结果与经典理论的结果进行了比较分析，结果表明，在集中力作用处和孔边处两种理论结果明显不同。     

Synthesis and characterization of magnetic polymer microspheres with a core-shell structure

Non-porous magnetic polymer microspheres with a core-shell structure were prepared by a novel micro-suspension polymerization technique. A stable iron oxide ferrofluid was used to supply the magnetic core, and the polymeric shell was made of glycidyl methacrylate （GMA monomer） and ethylene dimethacrylate （cross-linker）. In the preparation, polyvinyl alcohol was used as the stabilizer, and a lauryl alcohol mixture as the dispersant. The influence of various conditions such as aqueous phase volume, GMA and initiator amounts, reaction time and stirring speed on the character of the microspheres was investigated. The magnetic microspheres were then characterized briefly. The results indicate that the microspheres with active epoxy groups had a narrow size distribution range from 1 to 10 μm with a volume-weighted mean diameter of 4.5 μm. The saturation magnetization reached 19.9 emu/g with little coercivity and remanence.     

Friction factor and holdup studies for lubricated pipelining—I. Experiments and correlations

Results from new experiments on the lubricated pipelining of emulsified waxy crude oil and No. 6 fuel oil are presented and compared with other sources of literature. A correlation formula which estimates the holdup fraction is introduced and evaluated for all available experimental data. A simple theory is given which is based on the concentric core-annular flow model and leads to a Reynolds number and friction factor which reduce a large body of experimental data onto one curve; with the best results in the high Reynolds number flow regime.     

A STRESS VECTOR-BASED CONSTITUTIVE MODEL FOR COHESIONLESS SOIL (Ⅱ)-APPLICATION

The stress vector-based constitutive model for cohesionless soil, proposed by SHI Hong-yan et al., was applied to analyze the deformation behaviors of materials subjected to various stress paths. The result of analysis shows that the constitutive model can capture well the main deformation behavior of cohesionless soil, such as stress-strain nonlinearity, hardening property, dilatancy, stress path dependency, non-coaxiality between the principal stress and the principal strain increment directions, and the coupling of mean effective and deviatoric stress with deformation. In addition, the model can also take into account the rotation of principal stress axes and the influence of intermediate principal stress on deformation and strength of soil simultaneously. The excellent agreement between the predicted and measured behavior indicates the comprehensive applicability of the model. Biography: SHI Hong-yan (1962-), Associate Professor, Doctor     

The Wigner–Yanase information can increase under phase sensitive incoherent operations

We found that the Wigner-Yanase skew information, which has been recently proposed as a measure of coherence in Girolami (2014), can increase under a class of operations which may be interpreted as incoherent following the framework of Baumgratz et al., while being phase sensitive.     

Stability and phase transition of localized modes in Bose–Einstein condensates with both two- and three-body interactions

We investigate the stability and phase transition of localized modes in Bose–Einstein Condensates (BECs) in an optical lattice with the discrete nonlinear Schrödinger model by considering both two- and three-body interactions. We find that there are three types of localized modes, bright discrete breather (DB), discrete kink (DK), and multi-breather (MUB). Moreover, both two- and three-body on-site repulsive interactions can stabilize DB, while on-site attractive three-body interactions destabilize it. There is a critical value for the three-body interaction with which both DK and MUB become the most stable ones. We give analytically the energy thresholds for the destabilization of localized states and find that they are unstable (stable) when the total energy of the system is higher (lower) than the thresholds. The stability and dynamics characters of DB and MUB are general for extended lattice systems. Our result is useful for the blocking, filtering, and transfer of the norm in nonlinear lattices for BECs with both two- and three-body interactions.     

电磁感应透明的高阶非线性效应对光孤子的影响

研究了电磁感应透明介质中高阶非线性效应对光孤子传输的影响。采用半经典理论获得介质对光场的线性和非线性响应,基于介质特性利用波动理论推演出三-五阶非线性薛定谔方程。介质的线性非线性特性分别决定了群速度色散参量,三阶和五阶非线性系数。研究结果表明,该非线性介质既可以诱导亮孤子也可以诱导暗孤子,取决于群速度色散参量和三阶非线性系数。当前者为负同时后者为正时产生亮孤子,当两者均为负时产生暗孤子,二者可以通过载频与相应跃迁能级失谐的调节获得。与普通非线性薛定谔方程相比,三-五阶非线性薛定谔方程对亮孤子和暗孤子出现的参数和输入条件更加严格。     

基于659总线的飞行器电气控制系统设计与实现

为提高飞行器电气控制系统测量和管理的可靠性,实现电气控制系统的综合管理;通过采用ARINC659背板总线、冗余的电气控制系统模块化设计方法,设计并实现了一种电气控制系统。这篇文章介绍了该系统的主要功能、技术特点、硬件和软件设计。该系统在满足实时性、可靠性需求的同时,具有快速的系统重构和很强的可配置性,而且大大减少了飞机电气系统的重量,适应电气控制系统综合控制发展的方向。基于659总线的飞行器电气控制系统,解决了复杂机电系统的数据融合和综合管理,在工程实践中已成功应用。